JAIC 2002, Volume 41, Number 1, Article 5 (pp. 61 to 90)
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Journal of the American Institute for Conservation
JAIC 2002, Volume 41, Number 1, Article 5 (pp. 61 to 90)

THE SWELLING OF ARTISTS' PAINTS IN ORGANIC SOLVENTS. PART 2, COMPARATIVE SWELLING POWERS OF SELECTED ORGANIC SOLVENTS AND SOLVENT MIXTURES

ALAN PHENIX



NOTES

1. The measurements from separate experiments can be considered as a sample from an infinite population of possible measurements; and, likewise, the means of any series of measurements are a sample from the possible means of samples of measurements from the whole population. The distribution of the sample means is called the sampling distribution of the mean: its mean is the same as the mean of the original population. The standard error of the mean (SEM) is equivalent to the standard deviation of the sampling distribution of the mean (Miller and Miller 1993). The standard error of the mean can also be determined from the relationship between the standard deviation of the individual measurements, ς, and the sample size, n, following the equation: SEM = ς / √n, and this method has been used here.



REFERENCES

Banik, G., and G.Krist. 1984. L�sungsmittel in der Restaurierung. Vienna: ICCROM and Verlag der Apfel.

Blank, S., and C.Stavroudis. 1989. Solvents and sensibility. Western Association for Art Conservation Newsletter11(2):2–10.

Browne, F. L.1956. Swelling of oil paints in water. Part 8, Swelling of linseed oil paints in water and organic liquids.Forest Products Journal6:312–18.

Brunt, N. A.1962. The influence of swelling by water vapor on the mechanical properties of a polymer. Kolloid-Zeitschrift und Zeitschrift f�r Polymere185(2):119–25.

Brunt, N. A.1964. Blistering of paint layers as an effect of swelling by water.Journal of the Oil and Colour Chemists' Association47:31–42.

Cremonesi, P.2000. L'uso dei solventi organici nella pulitura di opere policrome. Padua: Il Prato.

Eissler, R. L., and L. H.Princen. 1968. Effect of some pigments on tensile and swelling properties of linseed oil films. Journal of Paint Technology40(518):105–11.

Eissler, R. L., and L. H.Princen. 1970. Swelling of linseed oil films in acid and alkaline environments. Journal of Paint Technology42(542):155–58.

Elm, A. C.1949. Deterioration of dried oil films.Industrial and Engineering Chemistry41:319–24.

Erhardt, D., and J. S.Tsang. 1990. The extractable components of oil paint film. In Cleaning, retouching, coatings,ed. J. S.Mills and P.Smith. London: International Institute for Conservation. 93–97.

Erhardt, D., C. S.Tumosa, and M. F.Mecklenburg. 2000. Natural and accelerated thermal aging of oil paint films. In Tradition and innovation,ed. A.Roy and P.Smith. London: International Institute for Conservation. 65–69.

Feller, R. L.1976. The relative solvent power needed to remove various aged solvent-type coatings. In Conservation and restoration of pictorial art,ed. N.Bromelle and P.Smith. London: International Institute for Conservation and Butterworths. 158–62.

Feller, R. L., N.Stolow, and E. H.Jones. 1971. On picture varnishes and their solvents. Rev. ed. Cleveland: Case Western Reserve University.

Feller, R. L., N.Stolow, and E. H.Jones. 1985. On picture varnishes and their solvents. Rev. and enlarged ed. 1985. Washington D. C.: National Gallery of Art.

Frilette, V. J.1946. Drying oil and oleoresinous varnish films: Increase in acidity on aging. Industrial and Engineering Chemistry38(5):493–96.

Hansen, C. M.2000. Hansen solubility parameters: A user's handbook. Boca Raton, Fla.: Chemical Rubber Company.

Hedley, G.1980. Solubility parameters and varnish removal: A survey. Conservator4:12–18. (Reprinted, with corrections, in Measured opinions [1993], ed. C.Villers. London: United Kingdom Institute for Conservation. 128–34.)

Kamlet, M. J., J.-L. M.Abboud, and R. W.Taft. 1983. Linear solvation energy relationships. Part 23, A comprehensive collection of solvatochromic parameters π*, α, β, and some methods for simplifying the general solvatochromatographic equation.Journal of Organic Chemistry48:2877–87.

Laurence, C., P.Nicolet, M.Tawfik Dalati, J.-L. M.Abboud, and R.Notario. 1994. The empirical treatment of solvent-solute interactions: 15 years of π*.Journal of Physical Chemistry98:5807–16.

Marcus, Y.1999. The Properties of solvents. Chichester, U. K.: John Wiley.

Michalski, S.1990. A physical model of the cleaning of oil paint. In Cleaning, retouching, coatings, ed. J. S.Mills and P.Smith. London: International Institute for Conservation. 85–92.

Miller, J. C., and J. N.Miller. 1993. Statistics for analytical chemistry3d ed.London: Ellis Horwood.

Mills, J. S., and R.White. 1999. The organic chemistry of museum objects. 2d ed.Oxford: Butterworth-Heinemann.

Phenix, A.1998a. The science and technology of the cleaning of pictures: Past, present and future. In Proceedings of 25th anniversary conference, School of Conservation, ed. K.Borchersen. Copenhagen: Royal Danish Academy of Art. 109–19.

Phenix, A.1998b. Solubility parameters and the cleaning of paintings: An update and review. Zeitschrift f�r Kunsttechnologie und Konservierung12(2):387–409.

Phenix, A2002. The swelling of artists'paints in organic solvents. Part 1, A simple method for measuring the inplane swelling of unsupported paint films. Journal of the American Institute for Conservation41:43–60.

Reichardt, C.1990. Solvents and solvent effects in organic chemistry. 2d ed.Cambridge: Wiley-VCH.

Ruhemann, H.1968. The cleaning of paintings. London: Faber and Faber.

Schilling, M. R., D. M.Carson, and H. R.Khanjian. 1999. Gas chromatographic determination of the fatty acid and glycerol content of lipids. Part 4, Evaporation of fatty acids and the formation of ghost images by framed oil paintings. In ICOM Committee for Conservation preprints, ed. J.Bridgland, 12th Triennial Meeting, Lyons, 1999. London: James and James. 1:248–53.

Schilling, M. R., H. R.Khanjian, and D. M.Carson. 1997. Fatty acid and glycerol content of lipids: Effects of aging and solvent extraction on the composition of paints.Techne5:71–78.

Schmid, P.1973. Extraction and purification of lipids. Part 2, Why is chloroform-methanol such a good lipid solvent?Physiological Chemistry and Physics5:141–50.

Stolow, N.1955. Some investigations of the action of solvents on drying oil films. Ph. D. diss., Courtauld Institute of Art, University of London.

Stolow, N.1957. The action of solvents on drying oil films. Part 1.Journal of the Oil and Colour Chemists' Association40:377–402.

Stolow, N.1963. Application of science to cleaning methods: Solvent action studies on pigmented and unpigmented linseed oil films. In Recent advances in conservation, ed. G.Thomson. London: Butterworths. 84–88.

Stolow, N1965. The application of gas chromatography in the investigation of works of art. In Application of science in the examination of works of art. Seminar held at the Museum of Fine Arts. Boston: Museum of Fine Arts. 172–83.

Stolow, N.1976. Solvent action. In Conservation and restoration of pictorial art, ed. N.Bromelle and P.Smith. London: International Institute for Conservation and Butterworths. 153–57.

Stoner, J. H.1994. The impact of research on the lining and cleaning of easel paintings.Journal of the American Institute for Conservation33:131–40.

Sutherland, K.2000. Personal communication. Scientific Research Division, National Gallery of Art, Washington, D.C.

Sutherland, K.2001. Solvent extractable components of oil paint films. Ph. D. diss., University of Amsterdam.

Sutherland, K., and N.Shibayama. 1999. The components of oil paint films extracted by organic solvents. In ICOM Committee for Conservation preprints, ed. J.Bridgland, 12th Triennial Meeting, Lyons, 1999. London: James and James. 1:341–46.

Tumosa, C. S., J.Millard, D.Erhardt, and M.Mecklenburg. 1999. Effects of solvents on the physical properties of paint films. In ICOM Committee for Conservation preprints,ed. J.Bridgland, 12th Triennial Meeting, Lyons, 1999. London: James and James. 1:347–52.

van den Berg, J. D. J., K. J.van den Berg, and J. J.Boon. 1999. Chemical changes in curing and ageing oil paints. In ICOM Committee for Conservation preprints, ed. J.Bridgland, 12th Triennial Meeting, Lyons, 1999. London: James and James. 1:248–53.

White, R., and A.Roy. 1998. GC-MS and SEM studies on the effects of solvent cleaning on old master paintings from the National Gallery, London.Studies in Conservation43:159–76.

Wolbers, R.2000. Cleaning painted surfaces: Aqueous methods. London: Archetype.


AUTHOR INFORMATION

ALAN PHENIX was educated at Leeds University, United Kingdom, receiving a B.Sc. Honors in chemistry and color chemistry combined in 1979. He studied conservation of easel paintings for three years at the Courtauld Institute of Art, University of London, and was awarded the institute's postgraduate diploma in 1984. After an internship at Tate Gallery, London, he worked as a paintings conservator in Australia, returning to Britain in 1989 to take up a teaching and research position at the Hamilton Kerr Institute, University of Cambridge. He was a lecturer in the Department of Conservation and Technology at the Courtauld Institute of Art from 1991 to 2000, during which time he spent 15 months on secondment to the MOLART (Molecular Aspects of Aging in Painted Works of Art) project managed by the Foundation for Fundamental Research on Matter, Institute for Atomic and Molecular Physics (FOM-AMOLF), Amsterdam. During 2001 he was research fellow at the Royal College of Art, London, and he has recently been appointed associate professor at the Institute for Archaeology, Art History and Conservation at the University of Oslo. He is presently coordinator of the ICOM-CC Working Group Paintings 1: Conservation and Restoration of Paintings. Address: Department of Conservation Studies, Institute for Archaeology, Art History and Conservation (IAKK), University of Oslo, Frederiks gt. 3, 0164 Oslo, Norway.


Copyright � 2002 American Institution for Conservation of Historic & Artistic Works