JAIC 2002, Volume 41, Number 3, Article 3 (pp. 243 to 254)
JAIC online
Journal of the American Institute for Conservation
JAIC 2002, Volume 41, Number 3, Article 3 (pp. 243 to 254)

ANTIFUNGAL PROTECTION AND SIZING OF PAPER WITH CHITOSAN SALTS AND CELLULOSE ETHERS. PART 1, PHYSICAL EFFECTS

MARIA DEL PILAR PONCE-JIM�NEZ, FERNANDO A. L�PEZ-DELLAMARY TORAL, & EZEQUIEL DELGADO FORNU�




REFERENCES

Aiba, S., Y.Fujiwara, T.Hideshima, C.Hwang, M.Kakizaki, M.Izume, N.Minoura, C. K.Rha, T.Shoij, A. J.Sinskey, and A.Tsutsumi. 1986. Filmogenic properties of chitin/chitosan. In Chitin in nature and technology, ed. R. A. A.Muzzarelli, C.Jeuniaux, and G. W.Gooday. New York: Plenum Press. 389–96.

Allan, G. G., J. R.Fox, G. D.Crosby, and K. V.Sarkanen. 1977. Chitosan, a mediator for fiber-water interactions in paper. Seattle: College of Forest Resources, University of Washington Press.

Caulfield, D. F., and D. E.Gunderson. 1990. Paper testing and strength characteristics. In Paper preservation: Current issues and recent developments, ed. P.Luner. Atlanta: Technical Association of the Pulp and Paper Industry. 31–40.

Dobroussina, S. A. D., T. D.Velikova, and O. V.Rybalchenko. 1996. A study on the biostability of parylene-coated paper. Restaurator17:75–85.

Domszy, J. G., G. K.Moore, and G. A. F.Roberts. 1985. The adsorption of chitosan on cellulose. In Cellulose and its derivatives: Chemistry, biochemistry and applications. Chichester, England, and New York: E. Horwood. 464–73.

Feller, R. L., and M.Wilt. 1990. Evaluation of cellulose ethers for conservation. In Research in conservation 3. Los Angeles: Getty Conservation Institute.

Garc�a-Ochoa, J. J.1988. Isolation and characterization of chitin from shrimp cuticle and transforming it into chitosan. Ph.D. diss., Guadalajara University, Guadalajara, Mexico.

Guilleumas, R.1972. Disinfecting and insect elimination of bibliographical reserves in the University and Provincial Library of Barcelona. Bolet�n de la Direcci�n General de Archivos y Bibliotecas125–26:111–25.

Kienzle-Sterner, C., D.Rodriguez-Sanchez, and C. K.Rha. 1984. Solution properties of chitosan chain conformation. In Chitin, chitosan and related enzymes. New York: Academic Press. 383–93.

Muzzarelli, R. A. A.1977. Chitin. Oxford: Pergamon. 220–28.

Muzzarelli, R. A. A., F.Tanfani, M.Emanueli, M. G.Muzzarelli, and G.Celia. 1981. The production of chitosans of superior quality. Journal of Applied Biochemistry3:316–21.

Page, D. H.1969. A theory for the tensile strength of paper. TAPPI52(4):674.

Ponce-Jim�nez, Maria del Pilar, Fernando A.L�pez-Dellamary Toral, and HumbertoGutierrez-Pulido. 2002. Antifungal protection and sizing of paper with chitosan salts and cellulose ethers. Part 2, Antifungal effects. Journal of the American Institute for Conservation41(2):255–68.

TAPPI. 1985. Zero-span breaking length of pulp, T231 cm-85. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1988. Hydrogen ion concentration (pH) of paper extracts (cold extraction method), T509 om-88. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1989. Folding endurance of paper (Schooper type tester), T423 om-89. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1990. Sampling and accepting a single lot of paper, paperboard, containerboard, or related product, T400 om-90. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1991. Viscosity of adhesives using a low-shear rotating apparatus, T666 om-91. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1992. Brightness of pulp, paper, and paperboard (directional reflectance at 457 nm), T452 om-92. Atlanta: Technical Association of the Pulp and Paper Industry.

TAPPI. 1993. Standard conditioning and testing atmospheres for paper, board, pulp hand-sheets, and related products, T402 om-93. Atlanta: Technical Association of the Pulp and Paper Industry.

Terayama, H.1950. Water-soluble chitosan. Japan (February 24):563.

Wolfrom, M. L., G. G.Maher, and A.Chaney. 1958. Chitosan nitrate. Journal of Organic Chemistry23:1990–91.



SOURCES OF MATERIALS

Filter paper

Whatman no. 1 Catalogue number H-06648-17 Equipar, S.A. de C.V. Juan S�nchez Azcona No. 1447 Colonia del Valle, delegaci�n Benito Ju�rez Mexico, D.F. C.P. 03100

Cellulose ethers

Methocel F4M Premium CMC and MC Droguer�a Cosmopolita S.A. de C.V. Av. Revoluci�n No. 1080 Col. Mixcoax Mexico City, Mexico

Chitosan

The chitosan was prepared from shrimp shells by the Chemical Laboratory of the Karl Augustin Grellman Institute of Wood, Cellulose, and Paper, University of Guadalajara. Autopista Guadalajara-Nogales, kil�metro 15.5 Las Agujas Municipio de Zapopan, Jalisco, Mexico Apartado Postal 52-93, C.P. 45020, Zapopan, Jalisco, Mexico

Roll hand-coater

RK Print-Coat Instruments Ltd. Royston Herts 5G8 OQZ, U.K.

Viscometer

Brookfield Engineering Laboratories 240 Cushing St. Stoughton, Mass. 02072


AUTHOR INFORMATION

MARIA DEL PILAR PONCE-JIM�NEZ received her biology degree from the National Autonomic University of Mexico and her master's degree from the University of Guadalajara with a specialty in cellulose and paper. Since 1990, she has been professor of conservation and restoration of paper and graphic documents at the National School of Conservation and Restoration and Museography at the Manuel del Castillo Negrete Institute of the National Institute of Anthropology and History (INAH) in Veracruz, Mexico. She also develops methods of teaching, application, and investigation in the field of paper conservation. Address: Centro INAH Veracruz, Benito Ju�rez No. 425 y 431, Zona Centro, C.P. 91700, Veracruz, Veracruz, Mexico.

FERNANDO A. L�PEZ-DELLAMARY TORAL received his B.S. from the National Autonomic University of Mexico and his Ph.D. from the University of Wisconsin at Madison. He is a professor of chemistry and analytical chemistry at the University of Guadalajara; chief of the chemistry laboratory at the University of Guadalajara's Karl Augustin Grellman Institute of Wood, Cellulose, and Paper; and director of investigation projects on paper technology, biochemistry, and forestry engineering. Address: Departamento de Madera, Celulosa y Papel Karl Augustin Grellman, Apartado Postal 52–93, C.P. 45020, Zapopan, Jalisco, Mexico.

EZEQUIEL DELGADO FORNU� received his B.S. in chemical engineering from the University of Guadalajara, his master's degree from the Karl Augustin Grellman Institute of Wood, Cellulose, and Paper at the University of Guadalajara, and his Ph.D. from University of Washington, Seattle, Washington, specializing in polymer chemistry and fiber science. He is a professor and researcher at the Karl Augustin Grellman Institute, specializing in chemical modification of fibers and polymers—natural and synthetic— and bioactive compounds such as chitosan. Address: Departamento de Madera, Celulosa y Papel Karl Augustin Grellman, Apartado Postal 52–93, C.P. 45020, Zapopan, Jalisco, Mexico.


Copyright � 2002 American Institution for Conservation of Historic & Artistic Works